Syntheses of sugar poly(orthoesters) through reverse anomeric effect.
نویسندگان
چکیده
High molecular weight sugar poly(orthoesters) were synthesized through reverse anomeric effect (RAE). We demonstrated that when RAE-enabled promoters, such as 4-(dimethylamino)pyridine (DMAP), triphenylphosphine (TPP) or imidazole, were employed, efficient polymerizations were achieved, giving sugar poly(orthoesters) with molecular weights up to 18 kDa.
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 32 شماره
صفحات -
تاریخ انتشار 2015