Syntheses of sugar poly(orthoesters) through reverse anomeric effect.

نویسندگان

  • Lingyao Li
  • Jun Wang
  • Melissa Obrinske
  • Ian Milligan
  • Kylie O'Hara
  • Lindsay Bitterman
  • Wenjun Du
چکیده

High molecular weight sugar poly(orthoesters) were synthesized through reverse anomeric effect (RAE). We demonstrated that when RAE-enabled promoters, such as 4-(dimethylamino)pyridine (DMAP), triphenylphosphine (TPP) or imidazole, were employed, efficient polymerizations were achieved, giving sugar poly(orthoesters) with molecular weights up to 18 kDa.

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عنوان ژورنال:
  • Chemical communications

دوره 51 32  شماره 

صفحات  -

تاریخ انتشار 2015